Additionally, the potential challenges of microplastic removal from treatment processes and remediation strategies of microplastics in drinking water were also put forward. The relationship between the properties and behavior of microplastics during different treatment processes is suggested to explore in the future.Prothioconazole is a fungicide that has been widely used in general agriculture and livestock husbandry. This study evaluated the acute toxicity of prothioconazole to zebrafish embryos by assessing their hatching rate and malformation when exposed to different concentrations of prothioconazole. The 96 h-LC50 value of zebrafish embryos was 1.70 mg/L. Upon exposure to 0.85 mg/L, the mortality rate of the embryos significantly increased while their hatching rate decreased significantly. At prothioconazole concentrations higher than 0.43 mg/L, developmental morphologic abnormalities such as heart and yolk-sac edema, spine curvature, tail deformity, shortened body length and decreased eye area were observed. The heart rate of embryos decreased in a dose-dependent fashion during the exposure time. Prothioconazole exposure also resulted in increased rates of cardiac malformation detected by significant increase in the distance between the sinus venosus and bulbus arteriosus and the pericardium area. Moreover, the expression levels of genes related to cardiac development (amhc, vmhc, fli1, hand2, gata4, nkx2.5, tbx5 and atp2a2a) were significantly altered after exposure to prothioconazole. Indeed, this study revealed the adverse effects on the developmental and cardiovascular system of zebrafish embryo caused by prothioconazole. It further elucidated the risk of prothioconazole exposure to vertebrate cardiovascular toxicity. As such, it provides a theoretical foundation for pesticide risk management measures.In this study, carbon quantum dots (CQDs) were used to decorate a TiO2/g-C3N4 (TCN) film electrode. The morphological, optical, and electrochemical properties of the TiO2/g-C3N4/CQDs nanorod arrays (TCNC NRAs) film were investigated using transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV-vis diffuse reflectance spectroscopy (DRS), photoluminescence (PL), and electrochemical impedance spectroscopy (EIS). The improved optical properties, photoelectrochemical properties and photoelectrocatalytic (PEC) performance of photoanode can be observed by doping CQDs onto the TCN NRAs film. Compared with TiO2 NRAs and TCN NRAs, the narrower band gap of 2.47 eV and longer lifetime of photoinduced electron-hole pairs were observed in the TCNC NRAs. Under visible light irradiation and a bias voltage of 1.2 V, the photocurrent density and 1,4-dioxane (1,4-D) removal rate of PEC process with TCNC NRAs electrode reached 0.16 mA/cm2 and 77.9%, respectively, which was 2.5 times and 1.5 times of that with TCN NRAs electrode. TCNC NRAs electrode could keep &gt;75% of the 1,4-D removal rate during five cycles tests. High PEC performance with TCNC NRAs electrode could be attributed to the enhanced charge separation and the change of electron transfer mechanism from typical heterojunction to Z-scheme, which may increase the active species production and change the dominant reactive species from O2?- to ?OH. Our experimental results should be useful for studying the degradation of 1,4-D and developing efficient PEC materials.This study is among the first to systematically study the electrochemical reduction of nitrate on boron-doped diamond (BDD) films with different surface terminations and boron-doping levels. The highest nitrate reduction efficiency was 48% and the highest selectivity in the production of nitrogen gas was 44.5%, which were achieved using a BDD electrode with a hydrogen-terminated surface and a B/C ratio of 1.0%. C-H bonds served as the anchor points for attracting NO3- anions close to the electrode surface, and thus accelerating the formation of NO3-(ads). Compared to oxygen termination, hydrogen-terminated BDD exhibited higher electrochemical reactivity for reducing nitrate, resulting from the formation of shallow acceptor states and small interfacial band bending. The hydrophobicity of the hydrogen-terminated BDD inhibited water electrolysis and the subsequent adsorption of atomic hydrogen, leading to increased selectivity in the production of nitrogen gas. A BDD electrode with a boron-doping level of 1.0% increased the density of acceptor states, thereby enhancing the conductivity and promoting the formation of C-H bonds after the cathodic reduction pretreatment leading to the direct reduction of nitrate.Abandoned mining and quarry areas are sources of potentially toxic elements (PTEs), through lixiviates or transfer processes of bioavailable fractions from mining wastes and tailings. In this study, earthworms (Eisenia fetida Savigny, 1826) were exposed for 28 days to two mining soils from a lead/zinc mine and two quarry soils from an old serpentine quarry. Despite their pseudo total metal contents, a previous characterization of these soils pointed out for a low chemical availability of PTEs. Therefore, a multibiomarker approach was used and the response of E. fetida to soils was assessed through the analysis of neurotoxic, oxidative stress, energy metabolism and DNA damage biomarkers (acetylcholinesterase, catalase, glutathione-s-transferase, lactate dehydrogenase, lipid peroxidation and DNA strand breaks). Metal bioaccumulation was also assessed to evaluate bioavailability and organism's exposure. Results showed that high contents of PTEs were recorded in the whole body of earthworms exposed to lead/zinc mine. However, the bioaccumulation factors for worms exposed to soils from both sampling sites were less then 1 due to the high PTEs contents in soils. Earthworms exposed to both types of soils displayed neurotoxic and energy metabolism effects. https://www.selleckchem.com/products/usp22i-s02.html However, significant levels of oxidative stress and DNA damage were recorded only for earthworms exposed to lead/zinc mine soils. This study demonstrated that despite the low availability of PTEs showed by previous sequential chemical extractions, the results obtained from the direct toxicity assessment performed in this study, highlight the importance of a multibiomarker approach using soil organisms to provide a better evaluation of soils pollution.